一、引言

　　1. Introduction

　　在全球“雙碳”戰(zhàn)略加速推進(jìn)與能源結(jié)構(gòu)深度變革的背景下，造紙行業(yè)作為傳統(tǒng)高耗能產(chǎn)業(yè)，正面臨減排壓力與資源化轉(zhuǎn)型的雙重挑戰(zhàn)。沼氣作為制漿廢水厭氧處理的副產(chǎn)物，其熱值潛力與碳中性特征使之成為造紙企業(yè)綠色轉(zhuǎn)型的關(guān)鍵突破口。然而，當(dāng)前行業(yè)普遍存在的沼氣利用率低（不足60%）、能源轉(zhuǎn)化模式粗放等問題，嚴(yán)重制約了其經(jīng)濟(jì)與環(huán)境價(jià)值的釋放。從我自己的實(shí)踐出發(fā)，原來采用的是沼氣摻燒工藝，2023年4月，我們開始調(diào)研，本著“多能互補(bǔ)”系統(tǒng)思維，以沼氣資源高效利用為核心，深度解構(gòu)沼氣提純、熱電聯(lián)產(chǎn)、生物天然氣制備等技術(shù)的協(xié)同創(chuàng)新路徑。通過對(duì)比分析鍋爐摻燒、沼氣發(fā)電、提純制氣三大模式的能效表現(xiàn)與經(jīng)濟(jì)性，結(jié)合太陽紙業(yè)企業(yè)的實(shí)證數(shù)據(jù)，得出結(jié)論：沼氣提純技術(shù)可以通過能源品位升級(jí)（甲烷濃度>95%）、碳資產(chǎn)增值（CCER開發(fā)）和多元化消納場景（車用燃?xì)?工業(yè)燃料）構(gòu)建復(fù)合價(jià)值網(wǎng)絡(luò)，實(shí)現(xiàn)最好的經(jīng)濟(jì)效益。

　　Against the backdrop of accelerated global "dual carbon" strategy and deep transformation of energy structure, the paper industry, as a traditional high energy consuming industry, is facing dual challenges of emission reduction pressure and resource transformation. Biogas, as a byproduct of anaerobic treatment of pulp wastewater, has the potential for calorific value and carbon neutrality, making it a key breakthrough for the green transformation of papermaking enterprises. However, the common problems in the current industry, such as low utilization rate of biogas (less than 60%) and extensive energy conversion mode, seriously restrict the release of its economic and environmental value. Starting from my own practice, we originally used the biogas co firing process. In April 2023, we began to investigate and, based on the "multi energy complementarity" system thinking, with the efficient utilization of biogas resources as the core, deeply deconstructed the collaborative innovation path of technologies such as biogas purification, cogeneration, and biogas production. By comparing and analyzing the energy efficiency performance and economy of the three major modes of boiler co firing, biogas power generation, and purified gas production, combined with empirical data from Sun Paper Industry, it is concluded that biogas purification technology can construct a composite value network through energy grade upgrading (methane concentration>95%), carbon asset appreciation (CCER development), and diversified consumption scenarios (vehicle gas/industrial fuel), achieving the best economic benefits.

　　二、沼氣特性概述

　　2、 Overview of Biogas Characteristics

　　2.1沼氣來源--厭氧處理工藝鏈（1）目前造紙廢水處理流程：初沉池→調(diào)節(jié)池→UASB/IC反應(yīng)器→好氧處理，其中UASB反應(yīng)器產(chǎn)氣占比達(dá)70%以上；

　　2.1 Source of Biogas - Anaerobic Treatment Process Chain (1) Currently, the papermaking wastewater treatment process includes: primary sedimentation tank → regulating tank → UASB/IC reactor → aerobic treatment, with UASB reactor producing more than 70% of the gas;

　　（2）造紙污泥的協(xié)同處理：造紙污泥（含纖維殘?jiān)┙?jīng)中溫（35-37℃）消化，產(chǎn)氣周期15-20天，VS（揮發(fā)性固體）降解率與產(chǎn)氣量呈正相關(guān)（VS每增加1%，產(chǎn)氣量提升0.5m/t）；

　　(2) Collaborative treatment of papermaking sludge: papermaking sludge (including fiber residue) is digested at medium temperature (35-37 ℃), with a gas production cycle of 15-20 days. The degradation rate of volatile solids (VS) is positively correlated with gas production (for every 1% increase in VS, the gas production increases by 0.5m/t);

　?。?）原料差異性影響：廢紙制漿沼氣含硫量高（HS>1500ppm），原生漿沼氣硫含量低（HS<800ppm）；非木漿（如竹漿）沼氣甲烷含量較木漿低3-5個(gè)百分點(diǎn)。2.2沼氣成分與熱值的動(dòng)態(tài)分析

　　(3) The impact of differences in raw materials: the sulfur content of waste paper pulp biogas is high (H-S>1500ppm), while the sulfur content of primary pulp biogas is low (H-S<800ppm); The methane content of non wood pulp (such as bamboo pulp) biogas is 3-5 percentage points lower than that of wood pulp. 2.2 Dynamic analysis of biogas composition and calorific value

　?。?）硫化氫處理必要性：HS濃度>200ppm時(shí)，燃?xì)庠O(shè)備腐蝕速率加快3倍（參考《燃?xì)廨啓C(jī)腐蝕控制標(biāo)準(zhǔn)GB/T 14090》）；脫硫成本占比：生物脫硫法0.1-0.2元/m，化學(xué)吸收法0.3-0.5元/m；

　　(1) The necessity of hydrogen sulfide treatment: When the concentration of H2S is greater than 200ppm, the corrosion rate of gas equipment accelerates by three times (refer to the "Gas Turbine Corrosion Control Standard GB/T 14090"); Cost proportion of desulfurization: 0.1-0.2 yuan/m  for biological desulfurization method, 0.3-0.5 yuan/m  for chemical absorption method;

　?。?）熱值波動(dòng)管理：甲烷濃度每下降5%，鍋爐熱效率降低2%；典型熱值應(yīng)用場景：發(fā)電需>22MJ/m，車用燃?xì)庑?gt;31MJ/m（需提純至CH>90%）。2.3體量測算模型（1）產(chǎn)氣量計(jì)算公式：Q =k×COD負(fù)荷×η×R其中： 

　　(2) Heat value fluctuation management: For every 5% decrease in methane concentration, the boiler thermal efficiency decreases by 2%; Typical application scenarios for calorific value: power generation requires>22MJ/m Does car gas require>31MJ/m (To be purified to CH>90%). 2.3 Volume Calculation Model (1) Gas Production Calculation Formula: Q=k × COD Load × η × R Where:

　　k：產(chǎn)氣系數(shù)（0.35-0.45m/kg COD）    

　　k: Gas production coefficient (0.35-0.45m/kg COD)      

　　η：COD去除率（85-95%）；    

　　η: COD removal rate (85-95%);      

　　R：運(yùn)行穩(wěn)定性系數(shù)（0.8-0.95）；

　　R: Operating stability coefficient (0.8-0.95);

　?。?）沼氣利用規(guī)模經(jīng)濟(jì)閾值：提純項(xiàng)目盈虧平衡點(diǎn)：沼氣量≥1500m/d；發(fā)電項(xiàng)目經(jīng)濟(jì)性拐點(diǎn)：設(shè)備利用率>75%（年運(yùn)行6500小時(shí)）。三、沼氣利用模式分析3.1自備熱電廠鍋爐摻燒模式摻燒模式是目前最普遍的沼氣利用模式，通過污水廠厭氧塔的沼氣穩(wěn)壓罐及后面的風(fēng)機(jī)，通過管道送到電廠的分氣缸，然后通過燃燒器后進(jìn)入鍋爐的燃燒系統(tǒng)。此模式的關(guān)鍵問題點(diǎn)我認(rèn)為有兩處：一是摻燒沼氣雖然投資小、系統(tǒng)簡單，但是其在鍋爐內(nèi)部的摻燒對(duì)鍋爐產(chǎn)生氮氧化物有很大影響，通過我實(shí)際的情況來看，一旦投入摻燒系統(tǒng)，脫硝用氨水量馬上增加。如果有兩個(gè)沼氣燃燒器運(yùn)行，就相當(dāng)于增加了兩個(gè)燃燒源，大大影響鍋爐氮氧化物的產(chǎn)生量。

　　(2) Scale economy threshold for biogas utilization: breakeven point for purification projects: biogas volume ≥ 1500m /d; Economic turning point of power generation projects: equipment utilization rate>75% (annual operation of 6500 hours). 3、 Analysis of Biogas Utilization Mode 3.1 Co firing Mode of Self provided Thermal Power Plant Boiler Co firing Mode is currently the most common biogas utilization mode. It is sent through the biogas stabilizing tank of the anaerobic tower in the sewage plant and the fan behind it, through pipelines to the power plant's gas separation cylinder, and then enters the combustion system of the boiler after passing through the burner. I think there are two key issues with this model: firstly, although the investment in co firing biogas is small and the system is simple, its co firing inside the boiler has a significant impact on the production of nitrogen oxides. Based on my actual situation, once the co firing system is put into use, the amount of ammonia water used for denitrification immediately increases. If there are two biogas burners running, it is equivalent to adding two combustion sources, greatly affecting the production of nitrogen oxides in the boiler.

　　二是沼氣熱值高，但是進(jìn)入爐膛后，實(shí)際產(chǎn)生的熱效率的大小需要試驗(yàn)確認(rèn)，也就是說，其產(chǎn)生的熱效率并不等于鍋爐熱效率。沼氣在燃煤鍋爐內(nèi)燃燒充分，但是到尾部換熱卻不能完全完成。我們組織了試驗(yàn)，沼氣投入鍋爐，穩(wěn)定燃燒后，在尾部煙氣處測量組份，沒有可燃元素，那就說明沼氣的燃盡率是100%；但同時(shí)發(fā)現(xiàn)鍋爐的排煙溫度馬上上升，排煙熱損失增加，說明在鍋爐內(nèi)沼氣燃燒熱效率是低于煤炭燃燒熱效率的。下面是實(shí)際的簡單試驗(yàn)的結(jié)果：

　　The second reason is that biogas has a high calorific value, but the actual thermal efficiency generated after entering the furnace needs to be confirmed through experiments, which means that the thermal efficiency generated does not equal the boiler thermal efficiency. Biogas is fully burned in coal-fired boilers, but the heat exchange at the tail cannot be fully completed. We organized an experiment and put biogas into the boiler. After stable combustion, the composition was measured at the tail flue gas. If there were no combustible elements, it means that the combustion rate of biogas is 100%; But at the same time, it was found that the exhaust temperature of the boiler immediately increased, and the exhaust heat loss increased, indicating that the thermal efficiency of biogas combustion in the boiler is lower than that of coal combustion. Here are the actual results of a simple experiment:

　　（1）沼氣輸入熱量：Q1=單位小時(shí)沼氣摻燒量*沼氣低位發(fā)熱量=1400m3*24.4mj/m3=81.58萬大卡；

　　(1) Biogas input heat: Q1=unit hour biogas co firing amount * biogas low-level heat generation=1400m3 * 24.4mj/m3=815800 kcal;

　　（2）排煙熱損失：Q2=12.8萬大卡

　　(2) Smoke exhaust heat loss: Q2=128000 kcal

　　（3）沼氣燃燒熱效率計(jì)算：η=1-Q/Q1=77.6%在我們這臺(tái)特定鍋爐中摻燒，沼氣在鍋爐實(shí)際熱效率為77.6%。如果5000大卡煤炭價(jià)格為800元，那一立方沼氣的經(jīng)濟(jì)價(jià)值是：24.4/4.1868/5000*800*0.77=0.72元。另外，需要提醒的是：“碳減排盲區(qū)”：摻燒模式因無法精確計(jì)量沼氣替代率，導(dǎo)致CCER（國家核證自愿減排量）開發(fā)難度大。

　　(3) Calculation of thermal efficiency of biogas combustion: η=1-Q/Q1=77.6%. In our specific boiler, when co fired, the actual thermal efficiency of biogas in the boiler is 77.6%. If the price of 5000 kcal coal is 800 yuan, the economic value of one cubic meter of biogas is 24.4/4.1868/5000 * 800 * 0.77=0.72 yuan. In addition, it should be noted that there is a "carbon emission reduction blind spot": the co firing mode is difficult to develop due to the inability to accurately measure the biogas substitution rate, making CCER (National Certified Voluntary Emission Reduction) challenging.

　　3.2沼氣發(fā)電模式考慮到現(xiàn)在企業(yè)經(jīng)濟(jì)情況不景氣，我們開始的項(xiàng)目原則就定位為“乙方投資，乙方運(yùn)維”的模式，我們把沼氣交于對(duì)方，對(duì)方提供電力和低壓工業(yè)用蒸汽給我方。具體配置及經(jīng)濟(jì)性核算如下：沼氣低熱值MJ24.4日供應(yīng)沼氣量m/d100000機(jī)組配置功率Mw13.80發(fā)電量Kw13310機(jī)組供電量Kw12645年運(yùn)行小時(shí)數(shù)h8000機(jī)組每小時(shí)蒸汽量t/h7.50供電供汽年度總收益萬元/年3739.單位沼氣價(jià)值元1.123.3沼氣提純模式沼氣提純制生物天然氣（Bio-CNG）模式，是通過膜分離、PSA（變壓吸附）或水洗工藝將沼氣甲烷濃度提純至90%~97%，生產(chǎn)車用燃?xì)饣蚬I(yè)燃料。此模式附加值最高（生物天然氣售價(jià)達(dá)3.5~4.5元/m），且可開發(fā)碳信用（CCER收益15~30元/噸CO）。下表是目前各提純工藝的優(yōu)劣勢的對(duì)比分析表：工藝名稱甲烷得率能耗適用規(guī)模核心優(yōu)勢主要局限變壓吸附90%~95%0.25~0.35>1000m/d自動(dòng)化高，純度穩(wěn)定吸附劑更換成本高膜分離80%~88%0.15~0.25200~2000m/d低能耗，模塊化靈活膜污染風(fēng)險(xiǎn)，預(yù)處理嚴(yán)格水洗法85%~90%0.3~0.5500~3000m/d脫碳徹底，工藝簡單水耗大，廢水處理難化學(xué)吸收（胺法）>99%0.4~0.6>1500m/d高純度，同步脫硫溶劑損耗，環(huán)保壓力深冷分離>99.5%0.8~1.2>5000m/d生產(chǎn)LNG，附加值極高投資與能耗雙高能耗單位：（kWh/m）

　　3.2 Considering the current economic downturn of the enterprise, our initial project principle was positioned as a "Party B investment, Party B operation and maintenance" model. We handed over the biogas to the other party, who provided us with electricity and low-pressure industrial steam. The specific configuration and economic calculation are as follows: the low calorific value of biogas MJ24.4, the daily supply of biogas m/d100000, the unit configuration power Mw13.80, the power generation Kw13310, the unit power supply Kw12645, the operating hours h8000, the hourly steam volume t/h7.50, the annual total revenue of power supply steam is RMB 3739. The unit biogas value is RMB 1.123.3. The biogas purification mode is to purify biogas to produce bio natural gas (Bio CNG), which purifies the methane concentration of biogas to 90%~97% through membrane separation, PSA (pressure swing adsorption) or water washing process, and produces vehicle gas or industrial fuel. This mode has the highest added value (the selling price of biogas reaches 3.5-4.5 yuan/m), and can also develop carbon credits (CCER income of 15-30 yuan/ton CO). The following table is a comparative analysis of the advantages and disadvantages of various purification processes at present: process name, methane yield, energy consumption, applicable scale, core advantages mainly limited to pressure swing adsorption 90%~95%, 0.25~0.35>1000m/d, high automation, stable purity, high adsorbent replacement cost, membrane separation 80%~88%, 0.15~0.25, 200~2000m/d, low energy consumption, modular flexible membrane pollution risk, strict pre-treatment, water washing method 85%~90%, 0.3~0.5500~3000m/d, complete decarbonization, simple process, high water consumption, difficult chemical absorption of wastewater treatment (amine method)>99%, 0.4~0.6>1500m/d, high purity, synchronous desulfurization solvent loss, environmental pressure cryogenic separation>99.5%, 0.8~1.2>5000m/d for LNG production, added value. High investment and energy consumption double high energy consumption unit: (kWh/m)

　　四、結(jié)論

　　4、 Conclusion

　　通過現(xiàn)場調(diào)研，我們?nèi)チ撕贾菖R港的現(xiàn)場考察，拿到第一手資料，所以經(jīng)過綜合論證，決定采用“沼氣提純”的模式來進(jìn)行沼氣資源的高效利用。從經(jīng)濟(jì)性角度看，每立方的沼氣產(chǎn)生的價(jià)值為：摻燒模式0.72元，沼氣發(fā)電模式約為1.12元，而沼氣提純模式，在目前能源條件下，由乙方負(fù)責(zé)投資和運(yùn)維的情況下，每方沼氣的價(jià)值將大于前面兩種模式。所以，我們選擇了沼氣提純模式來運(yùn)作此項(xiàng)目，也是企業(yè)能源工作在“多能互補(bǔ)”方面做出的一大有益嘗試。目前，太陽紙業(yè)是國內(nèi)唯一明確披露沼氣提純生產(chǎn)生物天然氣的造紙企業(yè)，其項(xiàng)目覆蓋國內(nèi)外多個(gè)基地，技術(shù)成熟且效益顯著。根據(jù)2019年數(shù)據(jù)，其山東基地的一、二期項(xiàng)目采用EPC模式建設(shè)，沼氣處理能力為2×30,000立方米/日，提純后的生物天然氣產(chǎn)量可達(dá)2×20,000立方米/日以上。截至2019年，山東基地已累計(jì)生產(chǎn)生物天然氣1,385萬立方米，直接并入廠區(qū)市政燃?xì)夤芫W(wǎng)，用于自用燃料，顯著降低對(duì)外部天然氣的依賴。以上，即關(guān)于造紙企業(yè)沼氣的高效利用項(xiàng)目的實(shí)踐總結(jié)，希望對(duì)相關(guān)企業(yè)的能源管理及項(xiàng)目決策起到一定的參考與借鑒作用。

　　Through on-site research, we went to Hangzhou Lingang for on-site investigation and obtained first-hand information. Therefore, after comprehensive evaluation, we have decided to adopt the "biogas purification" mode for efficient utilization of biogas resources. From an economic perspective, the value generated per cubic meter of biogas is: 0.72 yuan for co firing mode, about 1.12 yuan for biogas power generation mode, and the value per cubic meter of biogas purification mode will be greater than the previous two modes under current energy conditions, with Party B responsible for investment and operation. So, we chose the biogas purification mode to operate this project, which is also a beneficial attempt made by the enterprise's energy work in the aspect of "multi energy complementarity". At present, Sun Paper is the only paper-making enterprise in China that has explicitly disclosed the production of biogas through biogas purification. Its projects cover multiple bases both domestically and internationally, with mature technology and significant benefits. According to 2019 data, the first and second phases of its Shandong base project will be constructed using EPC mode, with a biogas processing capacity of 2 × 30000 cubic meters per day and a purified biogas production of over 2 × 20000 cubic meters per day. As of 2019, the Shandong base has produced a total of 13.85 million cubic meters of bio natural gas, which has been directly integrated into the municipal gas pipeline network in the factory area for self use as fuel, significantly reducing dependence on external natural gas. The above is a practical summary of the efficient utilization project of biogas in papermaking enterprises, hoping to provide some reference and guidance for energy management and project decision-making of related enterprises.